Home > Products > Materials Science P40 > 2,2'-Bipyrimidine

2,2'-Bipyrimidine

Catalog Number: EVT-309845

CAS Number: 34671-83-5

Molecular Formula: C8H6N4

Molecular Weight: 158.16 g/mol

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Product Introduction

Description

2,2’-Bipyrimidine is an organic compound with the formula (C4H3N2)2. It is a derivative of the heterocycle pyrimidine and is a white solid . The compound is used as a bridging ligand in coordination chemistry .

Synthesis Analysis

A high-yield synthesis was developed for the preparation of 2,2’-bipyrimidine using the Ullmann coupling of 2-iodopyrimidine. The new procedure was also used for the preparation of 4,4’,6,6’-tetramethyl-2,2’-bipyrimidine and 5,5’-dibromo-2,2’-bipyrimidine. The present review describes the homogenous catalytic methodologies for the synthesis of 2,2’-bipyridines involving C−C bond formation from C−H bond.

Molecular Structure Analysis

The 2,2’-bipyrimidine crystal belongs to the monoclinic system, space group P2,/n, with two molecules per unit cell each on a Ci site group.

Chemical Reactions Analysis

2,2’-Bipyrimidines have been shown to undergo multielectron reduction at low potentials. The major decomposition pathway was ultimately determined to be protonation of the dianion by solvent, which could be reversed by electrochemical or chemical oxidation.

Physical And Chemical Properties Analysis

2,2’-Bipyrimidine is an organic compound with the formula C8H6N4. Its molecular weight is 158.16 g/mol. It is a white solid.

Properties

CAS Number

34671-83-5

Product Name

2,2'-Bipyrimidine

IUPAC Name

2-pyrimidin-2-ylpyrimidine

Molecular Formula

C8H6N4

Molecular Weight

158.16 g/mol

InChI

InChI=1S/C8H6N4/c1-3-9-7(10-4-1)8-11-5-2-6-12-8/h1-6H

InChI Key

HKOAFLAGUQUJQG-UHFFFAOYSA-N

SMILES

C1=CN=C(N=C1)C2=NC=CC=N2

Canonical SMILES

C1=CN=C(N=C1)C2=NC=CC=N2

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