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Methyl 3-Methoxyacrylate

Catalog Number: EVT-3159878

CAS Number: 34846-90-7

Molecular Formula: C5H8O3

Molecular Weight: 116.11 g/mol

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Product Introduction

Description

Methyl 3-Methoxyacrylate is a laboratory chemical. It is also known as 2-Propenoic acid, 3-methoxy-, methyl ester .

Synthesis Analysis

Methyl 3-Methoxyacrylate can be synthesized from methyl vinyl ether and trichloroacetyl chloride as starting material via addition-elimination reaction, elimination reaction, haloform reaction, and elimination reaction. Another method involves the use of 3,3-dimethoxy methyl propionate through heating and gasifying, followed by a series of reactions catalyzed by p-Toluenesulfonic Acid agent.

Molecular Structure Analysis

The molecular formula of Methyl 3-Methoxyacrylate is C5H8O3. The molecular weight is 116.12.

Chemical Reactions Analysis

The [3+2] cycloaddition reaction between quinazoline-3-oxide and methyl 3-methoxyacrylate has been studied. This reaction is characterized by a completely ortho regioselectivity and a moderate exo stereoselectivity.

Physical And Chemical Properties Analysis

Methyl 3-Methoxyacrylate is a liquid at 20 degrees Celsius. It has a density of 1.0±0.1 g/cm3, a boiling point of 155.3±0.0 °C at 760 mmHg, and a flash point of 62.8±0.0 °C. It is soluble in water.

Properties

CAS Number

34846-90-7

Product Name

Methyl 3-Methoxyacrylate

IUPAC Name

methyl (E)-3-methoxyprop-2-enoate

Molecular Formula

C5H8O3

Molecular Weight

116.11 g/mol

InChI

InChI=1S/C5H8O3/c1-7-4-3-5(6)8-2/h3-4H,1-2H3/b4-3+

InChI Key

AUTCCPQKLPMHDN-ONEGZZNKSA-N

SMILES

COC=CC(=O)OC

Canonical SMILES

COC=CC(=O)OC

Isomeric SMILES

CO/C=C/C(=O)OC

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